Actinide Elements and their Compounds with other Elements. by R. Troc, W. Suski (auth.), H.P.J. Wijn (eds.) PDF

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By R. Troc, W. Suski (auth.), H.P.J. Wijn (eds.)

ISBN-10: 3540467297

ISBN-13: 9783540467298

ISBN-10: 354055114X

ISBN-13: 9783540551140

Volume 19 if crew III bargains with the magnetic homes of metals, alloys and steel compounds. the quantity of data on hand during this box isso sizeable that quantity III/19 needed to be cut up into a number of subvolumes. Subvolumes III/19a via III/19f deal with the intrinsic magnetic homes, i.e. these homes which count simply at the chemical composition and the crystal constitution. thus far, subvolumes III/19a, III/19b, III/19c, III/19d, III/19e and III/19f1 have seemed. Subvolume III/19f covers the magnetic homes of actinide components and their compounds. half 1 is anxious with the actinide parts and their compounds with 3d, 4d and 5d-elements. the current half 2 comprises info on compounds with major team parts. A finished index of gear for volumes III/19a ... III/19f is incorporated. info at the homes that rely on the training of the samples measured, as for example, skinny movies, amorphous alloys or the magnetic alloys utilized in technical functions, of III/19, viz. III/19g, III/19h and III/19i, of which III/19g, III/19h and III/19i2 have already been published.

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15 [90K2]. For smaller dopant atoms, such as SC, Y, Lu, Zr and Hf for which a, (MBe,,) < a, (UBe,,), y(O) per mol U is almost independent of concentration and amounts to 240% of that of pure UBe,,. , with the distance du-ac. 1 limit (nonconcentrated regime). Fig. 57. UBe,,. f-derived specific heat, AC = CexpC,,, vs. log T [86Fl]. Cph is the lattice contribution determined from neutron inelastic scattering. The solid line is a Kondo contribution, the dashed line is a Schottky anomaly for doublet-quartet splitting (180 K).

6 A I Kondo singlet Kondo coherence --__ 0 20 40 60 80 kbor 100 P- Fig. 39. UBe,,. Effect of pressure on characteristic temperatures. Kondo temperature TK, Kondo coherence temperature Tcohand superconducting temperature T, [89A2]. For discussion and the way of inferring these temperatures seethe original paper. LandoMGmswin New Suia 111/19f2 Ref. p. 1 An-Be: figures 20 pV/K 15 I I I I 4lY-l-l - ’ 0’ p[kbarl poHITI 0 10 I 23 Zh ? 5 K I! 0 T- / ... I I I I 5 10 15 20 25 K 30 T- b Fig. 40. UBe,,. (a) Low-temperature electrical resistivity p at four different pressures (indicated in the figure) taken at 0 and 6 T for polycrystalline UBe, a [88Ml].

28b. Also consistent with earlier work [SSBl]. pSR in U,,,,,Th,,,,,Be,, provides definitive evidence for the onset of weak magnetism at temperature Ts2 below the normal superconducting transition at T,,. The transition at T,, is of second order with a magnetic moment (10m3... lo-*) ne/Sf atom [89H2]. There is no indication of magnetic ordering from NMR spectra [84Ml]. o- 12 3 4 5 6x1 x- ‘Joe13 Fig. 30. (U,Th)Be,,. Superconducting transition temperature T,, vs. composition x for polycrystalline U, -XTh,Be,3, at pressuresfrom 0 to 12 kbar [86Ll].

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Actinide Elements and their Compounds with other Elements. Part 2 by R. Troc, W. Suski (auth.), H.P.J. Wijn (eds.)


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